THERMODYNAMICS - THEORY
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Energy
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Chemical Energy Transfers to
Kinetic Energy in Rocket
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Energy is the capacity for doing work. It
may exist in a variety of forms such as thermal, mechanical,
kinetic, potential, electric, magnetic, chemical, and nuclear. It
may be transferred from one type of energy
to another. For example,
- Heating water by gas:
Chemical energy ---> thermal energy
- Heating water by electricity:
electric energy ---> thermal energy
- Running nuclear power plant:
Nuclear energy ---> electric energy
- Flying rocket:
Chemical energy ---> thermal Energy ---> Kinetic Energy
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Forms of Energy
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Kinetic Energy and Gravitational
Potential Energy
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Kinetic Energy (KE): The energy that a system possesses
as a result of its motion.
KE = mv2/2
where
m = mass of the system
v = velocity of the system
If an object of mass m changes velocity from v1 to v2.
thus the change of its kinetic energy is:
ΔKE =
1/2 (v2 2- v1 2)
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Potential Energy (PE): The energy that a system possesses
as a result of its elevation in a gravitational field or change of configurations.
Gravitational potential energy (elevation in a gravitational field):
PE = mgz
where
m = mass of the system
z = height relative to a reference frame
Moving an object from location A to B, its gravitational potential
energy change is:
ΔPE = mg(ZB - ZA)
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Elastic Potential Energy
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Elastic potential energy (change of configurations):
PE = 1/2 kx2
where k = spring constant
x = change in spring length
If a spring elongates from L1 to L2, the elastic
potential energy stored in the spring is :
ΔPE = 1/2 k L2 2-
1/2 k L1 2
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Molecules Random Movement
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Internal energy (U): The energy associated with the
random, disordered motion of molecules. It is the sum of the kinetic
and potential energies of all molecules.
- Experience has shown that for most substances with no phase change
involved, internal energy strongly depends on temperature. Its dependence
on pressure and volume is relatively small.
- It is not possible to calculate the absolute value of the internal
energy of a body. Only internal energy change of a system can be determined.
- Internal energy is a property.
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Total Energy (E): The sum of all forms of energy exist
in a system. The total energy of a system that consists of kinetic,
potential, and internal energies is expressed as:
E = U + KE + PE = U + mv2/2
+ mgz
The change in the total energy of a system is:
ΔE = ΔU
+ ΔKE + ΔPE
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Enthalpy (H)
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Enthalpy is a thermodynamics property of a substance and is defined as the sum of its internal energy and the product of its pressure and volume.
H = U + PV
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Specific Heat (c)
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Experiment shows that the temperature rise
of liquid water due to heat transfer to the water is given by
Q = m c (T2 - T1)
where Q = heat transfer to the water
m = mass of water
T2 - T1 = temperature
rise of the water
c = specific heat, an experiment factor
In general, the value of specific heat c depends on the substance in the
system, the change of state involved, and the particular state of the
system at the time of transferring heat. Specific heat of solids and liquids
is only a function of temperature but specific heat of gaseous substances
is a function of temperature and process. |
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Specific Heat at Constant Volume (cv)
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Isochoric Process |
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Specific heat at constant volume is the change
of specific internal energy with respect to temperature when the volume
is held constant (Isochoric process).
For constant volume process:
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Specific Heat at Constant Pressure (cP)
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Isobaric Process
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Specific heat at constant pressure is the change
of specific enthalpy with respect to temperature when the pressure is held
constant (Isobaric process).
For constant pressure process
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